Research
The impact of dissolved organic matter (DOM) structure on phototransformation pathways of organochlorine contaminants.
Chlorinated organic contaminants often enter waterbodies through accidental spills or municipal wastewater effluents. Surface water in streams, rivers, and lakes contains diverse dissolved organic matter (DOM), a complex mixture of molecules from plant material and microorganisms. The structure of DOM strongly depends on the source of origin. When exposed to sunlight, these chlorinated contaminants interact with the dissolved organic matter and sunlight, breaking down into daughter products. The daughter products may be different depending on the DOM type.
In this research direction, we study the mechanism of the degradation of organic contaminants in simulated laboratory experiments using the light source in the UVA-visible wavelength region.
Understanding the biogeochemical processes in surface water under climate change.
Freshwater lakes are essential sources of public water supply for drinking purposes. Dissolved organic matter (DOM) is a natural water component and primary precursor of disinfection byproducts (DBPs) during raw water disinfection. The profile and concentration of the formed DBPs depend on the molecular composition of DOM and its secondary alterations in water. Biodegradation and phototransformation can increase or decrease the reactivity of DOM toward DBP formation and strongly depend on the DOM properties. This research endeavor will identify the drivers of DBP formation in the lakes that serve as drinking water supply under climate change scenarios.
In this research project, we combine laboratory experiments with field sampling to better understand the biogeochemical processes in surface water.
Our main sampling location is Lake Okeechobee - the largest freshwater lake in the state of Florida (USA).
Identifying the drivers of contaminant mixture toxicity in the aquatic environment.
When organic contaminants are released into the aquatic environment, they transform into a mixture of daughter products. These daughter products can be more toxic to the ecosystem and human health. The chemical composition and characteristics of natural water can influence the formation of these products.
In this research direction, we study how water chemical characteristics, such as pH, composition, and concentration of dissolved organic matter (DOM), impact the toxicological profile of the degradation products. Our goal is to identify the factors driving the formation of higher toxicity products in surface water.
This interdisciplinary and highly collaborative research combines environmental chemistry, ecotoxicology, and machine learning approaches.
Our collaborators
We are a highly collaborative group, always seeking partnerships to enhance our understanding of the fate of environmental contaminants and their impact on ecosystems and human health.
FAU:
Dr. Yalan Liu, Civil, Assistant Professor, Department of Civil, Environmental and Geomatics Engineering
External:
Funded Research
- NSF Environmental Chemical Sciences. Organochlorine Contaminant Phototransformation: Exploring the Impact of Dissolved Organic Matter Molecular Composition. PIs: Dr. Natalia Malina, Dr. Ann Ojeda. Amount: $424,356. 2024-2027
- Mississippi-Alabama Sea Grant Program. Inequities in pollution exposure: examining the relationship between onsite wastewater system prevalence and water contamination. PI: Dr. Stephanie Rogers. Dr. Malina’s role: co-PI. Amount: $306,000. 2024-2025